Measurement of cyclic volatile methylsiloxanes in the aquatic environment 1 using low - density polyethylene passive sampling devices using an in - field 2 calibration study – challenges and guidance 3

نویسندگان

  • Janine Bruemmer
  • Raquel Falcon
  • Richard Greenwood
  • Graham A. Mills
  • Colin Hastie
  • Christopher Sparham
  • Roger van Egmond
چکیده

14 Cyclic volatile methylsiloxanes (cVMS) are used in personal care products and are 15 hydrophobic, volatile and persistent. Their environmental water concentrations are low and 16 are difficult to detect using conventional sampling methods. This study shows the potential of 17 passive sampling for cVMS. We used low-density polyethylene (LDPE) samplers and in-field 18 calibration methods for octamethylcyclotetrasiloxane (D4) and 19 decamethylcyclopentasiloxane (D5). 13 C-D4 and 13 C-D5, methyltris(trimethylsiloxy)silane 20 (MT), tetrakis(trimethylsiloxy)silane (TK), and five deuterated polycyclic aromatic 21

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تاریخ انتشار 2014